Chelate Control of Diiron(I) Dithiolates Relevant to the [Fe–Fe]-Hydrogenase Active Site

The reaction of Fe(2)(S(2)C(2)H(4))(CO)(6) with cis-Ph(2)PCH=CHPPh(2) (dppv) yields Fe(2)(S(2)C(2)H(4))(CO)(4)(dppv), 1(CO)(4), wherein the dppv ligand is chelated to a single iron center. NMR analysis indicates that in 1(CO)(4), the dppv ligand spans axial and basal coordination sites. In addition...

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Main Authors: Justice, Aaron K., Zampella, Giuseppe, De Gioia, Luca, Rauchfuss, Thomas B., van der Vlugt, Jarl Ivar, Wilson, Scott R.
格式: Artigo
語言:Inglês
出版: 2007
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC2430879/
https://ncbi.nlm.nih.gov/pubmed/17279743
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic0618706
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