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Chelate Control of Diiron(I) Dithiolates Relevant to the [Fe–Fe]-Hydrogenase Active Site
The reaction of Fe(2)(S(2)C(2)H(4))(CO)(6) with cis-Ph(2)PCH=CHPPh(2) (dppv) yields Fe(2)(S(2)C(2)H(4))(CO)(4)(dppv), 1(CO)(4), wherein the dppv ligand is chelated to a single iron center. NMR analysis indicates that in 1(CO)(4), the dppv ligand spans axial and basal coordination sites. In addition...
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| Huvudupphovsmän: | , , , , , |
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| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2007
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2430879/ https://ncbi.nlm.nih.gov/pubmed/17279743 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic0618706 |
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