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Diiron Azadithiolates as Models for the [FeFe]-Hydrogenase Active Site and Paradigm for the Role of the Second Coordination Sphere

The [FeFe] hydrogenases (H(2)ases) catalyze the redox reaction that interconverts protons and H(2). This area of biocatalysis has attracted attention because the metal-based chemistry is unusual, and the reactions have practical implications. The active site consists of a [4Fe–4S] cluster bridged to...

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Detaylı Bibliyografya
Yayımlandı:Acc Chem Res
Yazar: Rauchfuss, Thomas B.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2015
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC4797653/
https://ncbi.nlm.nih.gov/pubmed/26079848
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.accounts.5b00177
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