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Characterization of a Borane σ Complex of a Diiron Dithiolate: Model for an Elusive Dihydrogen Adduct
[Image: see text] The azadithiolate complex Fe(2)[(SCH(2))(26)NMe](CO)(6) reacts with borane to give an initial 1:1 adduct, which spontaneously decarbonylates to give Fe(2)[(SCH(2))(2)NMeBH(3)](CO)(5). Featuring a Fe–H–B three-center, two-electron interaction, the pentacarbonyl complex is a structur...
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| Publicat a: | Organometallics |
|---|---|
| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2017
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5538135/ https://ncbi.nlm.nih.gov/pubmed/28781407 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.7b00236 |
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