Lataa...
Characterization of a Borane σ Complex of a Diiron Dithiolate: Model for an Elusive Dihydrogen Adduct
[Image: see text] The azadithiolate complex Fe(2)[(SCH(2))(26)NMe](CO)(6) reacts with borane to give an initial 1:1 adduct, which spontaneously decarbonylates to give Fe(2)[(SCH(2))(2)NMeBH(3)](CO)(5). Featuring a Fe–H–B three-center, two-electron interaction, the pentacarbonyl complex is a structur...
Tallennettuna:
| Julkaisussa: | Organometallics |
|---|---|
| Päätekijät: | , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2017
|
| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5538135/ https://ncbi.nlm.nih.gov/pubmed/28781407 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.7b00236 |
| Tagit: |
Lisää tagi
Ei tageja, Lisää ensimmäinen tagi!
|