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Computational and Experimental Investigations of the Fe(2)(μ-S(2))/Fe(2)(μ-S)(2) Equilibrium
Density functional theory (DFT) calculations on Fe(2)S(2)(CO)(6−2n)(PMe(3))(2n) for n = 0, 1, and 2 reveal that the most electron-rich derivatives (n = 2) exist as diferrous disulfides lacking an S–S bond. The thermal interconversion of the Fe(II)(2)(S)(2) and Fe(I)(2)(S(2)) valence isomers is symme...
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| Publicado no: | Inorg Chem |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8100967/ https://ncbi.nlm.nih.gov/pubmed/33650855 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.0c03709 |
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