Redox and “Antioxidant” Properties of Fe(2)(μ-SH)(2)(CO)(4)(PPh(3))(2)

The chemistry of Fe(2)(μ-SH)(2)(CO)(4)(PPh(3))(2) (2(HH)) is described with attention to S-S coupling reactions. Produced by reduction of 2 (Fe(2)(μ-S(2))(CO)(4)(PPh(3))(2)), 2(HH) is an analogue of Fe(2)(μ-SH)(2)(CO)(6) (1(HH)) that exhibits well-behaved S-centered redox. Both 2(HH) and the related...

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Vydáno v:Inorg Chem
Hlavní autoři: Kagalwala, Husain N., Lalaoui, Noemie, Li, Qian-Li, Liu, Liang, Woods, Toby, Rauchfuss, Thomas B.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2019
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6402951/
https://ncbi.nlm.nih.gov/pubmed/30724559
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.8b03344
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