Bioinspired Hydrogenase Models: The Mixed-Valence Triiron Complex [Fe(3)(CO)(7)(μ-edt)(2)] and Phosphine Derivatives [Fe(3)(CO)(7–x)(PPh(3))(x)(μ-edt)(2)] (x = 1, 2) and [Fe(3)(CO)(5)(κ(2)-diphosphine)(μ-edt)(2)] as Proton Reduction Catalysts

[Image: see text] The mixed-valence triiron complexes [Fe(3)(CO)(7–x)(PPh(3))(x)(μ-edt)(2)] (x = 0–2; edt = SCH(2)CH(2)S) and [Fe(3)(CO)(5)(κ(2)-diphosphine)(μ-edt)(2)] (diphosphine = dppv, dppe, dppb, dppn) have been prepared and structurally characterized. All adopt an anti arrangement of the dith...

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Detalhes bibliográficos
Main Authors: Rahaman, Ahibur, Ghosh, Shishir, Unwin, David G., Basak-Modi, Sucharita, Holt, Katherine B., Kabir, Shariff E., Nordlander, Ebbe, Richmond, Michael G., Hogarth, Graeme
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3985925/
https://ncbi.nlm.nih.gov/pubmed/24748710
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om400691q
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