Synthetic Designs and Structural Investigations of Biomimetic Ni-Fe Thiolates

Described are the syntheses of several Ni(μ-SR)(2)Fe complexes, including hydride derivatives, in a search for improved models for the active site of [NiFe]-hydrogenases. The nickel(II) precursors include (i) nickel with tripodal ligands: Ni(PS(3))(−) and Ni(NS(3))(−) (PS(3)(3-) = tris(phenyl-2-thio...

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Publicado en:Inorg Chem
Main Authors: Basu, Debashis, Bailey, T. Spencer, Lalaoui, Noemie M., Richers, Casseday P., Woods, Toby J., Rauchfuss, Thomas B., Arrigoni, Federica, Zampella, Giuseppe
Formato: Artigo
Idioma:Inglês
Publicado: 2019
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6379113/
https://ncbi.nlm.nih.gov/pubmed/30707014
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.8b02991
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