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Hydrogen Activation by Biomimetic [NiFe]-Hydrogenase Model Containing Protected Cyanide Cofactors
Described are experiments that allow incorporation of cyanide cofactors and hydride substrate into active site models [NiFe]-hydrogenases (H(2)ases). Complexes of the type (CO)(2)(CN)(2)Fe(pdt)Ni(dxpe), (dxpe = dppe, 1; dxpe = dcpe, 2) bind the Lewis acid B(C(6)F(5))(3) (BAr(F)(3)) to give the adduc...
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| Autori principali: | , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2013
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3843950/ https://ncbi.nlm.nih.gov/pubmed/23899049 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja404580r |
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