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Connecting [NiFe]- and [FeFe]-Hydrogenases: Mixed-Valence Nickel-Iron Dithiolates With Rotated Structures
A series of mixed-valence iron-nickel dithiolates is described that exhibits structures similar to those of mixed-valence diiron dithiolates. Interaction of tricarbonyl salt [(dppe)Ni(pdt)Fe(CO)(3)]BF(4) ([1]BF(4), dppe = Ph(2)PCH(2)CH(2)PPh(2), pdtH(2) = HSCH(2)CH(2)CH(2)SH) with P-donor ligands (L...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3432505/ https://ncbi.nlm.nih.gov/pubmed/22838645 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic300910r |
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