Mixed-Valence Nickel-Iron Dithiolate Models of the [NiFe]-Hydrogenase Active Site

A series of mixed-valence iron-nickel dithiolates is described. Oxidation of (diphosphine)Ni(dithiolate)Fe(CO)(3) complexes 1, 2, and 3 with ferrocenium salts affords the corresponding tricarbonyl cations [(dppe)Ni(pdt)Fe(CO)(3)](+) ([1](+)), [(dppe)Ni(edt)Fe(CO)(3)](+) ([2](+)) and [(dcpe)Ni(pdt)Fe...

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Autors principals: Schilter, David, Nilges, Mark J., Chakrabarti, Mrinmoy, Lindahl, Paul A., Rauchfuss, Thomas B., Stein, Matthias
Format: Artigo
Idioma:Inglês
Publicat: 2012
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Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3288512/
https://ncbi.nlm.nih.gov/pubmed/22304696
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic202329y
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