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Synthesis and vibrational spectroscopy of (57)Fe-labeled models of [NiFe] hydrogenase: first direct observation of a nickel–iron interaction
A new route to iron carbonyls has enabled synthesis of (57)Fe-labeled [NiFe] hydrogenase mimic (OC)(3) (57)Fe(pdt)Ni(dppe). Its study by nuclear resonance vibrational spectroscopy revealed Ni–(57)Fe vibrations, as confirmed by calculations. The modes are absent for [(OC)(3) (57)Fe(pdt)Ni(dppe)](+),...
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| Hauptverfasser: | , , , , , , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2014
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4191989/ https://ncbi.nlm.nih.gov/pubmed/25237680 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4cc04572f |
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