Models of the Ni-L and Ni-SI(a) States of the [NiFe]-Hydrogenase Active Site

A new class of synthetic models for the active site of [NiFe]-hydrogenases are described. The Ni(I/II)(SCys)(2) and Fe(II)(CN)(2)CO sites are represented with (RC(5)H(4))Ni(I/II) and Fe(II)(diphos)(CO) modules, where diphos = 1,2-C(2)H(4)(PPh(2))(2)(dppe) or cis-1,2-C(2)H(2)(PPh(2))(2)(dppv). The tw...

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Bibliographic Details
Published in:Inorg Chem
Main Authors: Chambers, Geoffrey M., Huynh, Mioy T., Li, Yulong, Hammes-Schiffer, Sharon, Rauchfuss, Thomas B., Reijerse, Edward, Lubitz, Wolfgang
Format: Artigo
Language:Inglês
Published: 2015
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4807737/
https://ncbi.nlm.nih.gov/pubmed/26421729
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.5b01662
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