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Molecular Basis for Olefin Rearrangement in the Gephyronic Acid Polyketide Synthase

Polyketide synthase (PKS) are a rich source of natural products of varied chemical composition and biological significance. Here, we report the characterization of an atypical dehydratase (DH) domain from the PKS pathway for gephyronic acid, an inhibitor of eukaryotic protein synthesis. Using a libr...

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Pubblicato in:ACS Chem Biol
Autori principali: Dodge, Greg J., Ronnow, Danialle, Taylor, Richard E., Smith, Janet L.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2018
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6233718/
https://ncbi.nlm.nih.gov/pubmed/30179448
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acschembio.8b00645
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