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Stereoselective Synthesis of Dihydroisocoumarin Moiety of Microbial Agent AI-77-B: a Diels-Alder Based Strategy
The dihydroisocoumarin fragment of the gastroprotective natural product AI-77-B has been synthesized in optically active form by using a regiospecific Diels-Alder reaction of 1-methoxy-1,3-cyclohexadiene and an acetylenic ester derivative, prepared stereoselectively from leucinal.
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| Published in: | Tetrahedron Lett |
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| Main Authors: | , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
1999
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6226092/ https://ncbi.nlm.nih.gov/pubmed/30422131 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/S0040-4039(98)01977-7 |
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