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Asymmetric hetero Diels-Alder route to quaternary carbon centers: synthesis of (−)-malyngolide
Conformationally constrained chiral bis(oxazoline)-metal complex catalyzed asymmetric hetero Diels-Alder reactions of Danishefsky’s diene and a variety of α-keto esters constructed quaternary carbon centers enantioselectively. The reaction was utilized in the synthesis of (−)-malyngolide.
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| Udgivet i: | Tetrahedron Lett |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2001
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6214206/ https://ncbi.nlm.nih.gov/pubmed/30393409 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/S0040-4039(01)01227-8 |
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