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ASYMMETRIC HETERO DIELS-ALDER REACTIONS OF DANISHEFSKY’S DIENE AND GLYOXYLATE ESTERS CATALYZED BY CHIRAL BISOXAZOLINE DERIVED CATALYSTS
Asymmetric hetero Diels-Alder reactions of Danishefsky’s diene and glyoxylate esters catalyzed by bis(oxazoline)-metal complex afforded the corresponding aldol adduct which upon treatment with trifluoroacetic acid furnished the hetero Diels-Alder product in 72% enantiomeric excess and 70% isolated y...
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| Publié dans: | Tetrahedron Asymmetry |
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| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
1998
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6214153/ https://ncbi.nlm.nih.gov/pubmed/30395656 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/0957-4166(96)00261-3 |
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