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ASYMMETRIC HETERO DIELS-ALDER REACTIONS OF DANISHEFSKY’S DIENE AND GLYOXYLATE ESTERS CATALYZED BY CHIRAL BISOXAZOLINE DERIVED CATALYSTS

Asymmetric hetero Diels-Alder reactions of Danishefsky’s diene and glyoxylate esters catalyzed by bis(oxazoline)-metal complex afforded the corresponding aldol adduct which upon treatment with trifluoroacetic acid furnished the hetero Diels-Alder product in 72% enantiomeric excess and 70% isolated y...

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Detalhes bibliográficos
Publicado no:Tetrahedron Asymmetry
Main Authors: Ghosh, Arun K., Mathivanan, Packiarajan, Cappiello, John, Krishnan, K.
Formato: Artigo
Idioma:Inglês
Publicado em: 1998
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6214153/
https://ncbi.nlm.nih.gov/pubmed/30395656
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/0957-4166(96)00261-3
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