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Conformationally Constrained Bis(oxazoline) Derived Chiral Catalyst : A Highly Effective Enantioselective Diels-Alder Reaction
The reaction of cyclopentadiene with various bidentate dienophiles in the presence of 4–10 mol% of copper(II)-bis(oxazoline) complexes afforded excellent endo/exo selectivity as well as endo enantioselectivity (95–99% ee) and isolated yields. On the other hand, Diels-Alder reaction with Mg(II)-compl...
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| Udgivet i: | Tetrahedron Lett |
|---|---|
| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
1999
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6219759/ https://ncbi.nlm.nih.gov/pubmed/30411722 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/0040-4039(96)00721-6 |
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