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Asymmetric hetero-Diels–Alder reaction catalyzed by dirhodium(II) carboxamidates

Chiral dirhodium(II) carboxamidates are highly efficient catalysts for reactions between a variety of aldehydes and activated dienes. Catalyst loadings as low at 0.01 mol % have been realized with enantioselectivities up to 97%. Kinetic investigations reveal a pronounced electronic influence on the...

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Detalhes bibliográficos
Main Authors: Doyle, Michael P., Valenzuela, Marcela, Huang, Penglin
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2004
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC397391/
https://ncbi.nlm.nih.gov/pubmed/15060277
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0307025101
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