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Asymmetric hetero-Diels–Alder reaction catalyzed by dirhodium(II) carboxamidates

Chiral dirhodium(II) carboxamidates are highly efficient catalysts for reactions between a variety of aldehydes and activated dienes. Catalyst loadings as low at 0.01 mol % have been realized with enantioselectivities up to 97%. Kinetic investigations reveal a pronounced electronic influence on the...

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Bibliografski detalji
Izdano u:Proc Natl Acad Sci U S A
Glavni autori: Doyle, Michael P., Valenzuela, Marcela, Huang, Penglin
Format: Artigo
Jezik:Inglês
Izdano: National Academy of Sciences 2004
Teme:
Online pristup:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC397391/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/15060277/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.0307025101
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