Asymmetric hetero-Diels–Alder reaction catalyzed by dirhodium(II) carboxamidates
Chiral dirhodium(II) carboxamidates are highly efficient catalysts for reactions between a variety of aldehydes and activated dienes. Catalyst loadings as low at 0.01 mol % have been realized with enantioselectivities up to 97%. Kinetic investigations reveal a pronounced electronic influence on the...
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| Publicado no: | Proc Natl Acad Sci U S A |
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| Principais autores: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2004
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC397391/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/15060277/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.0307025101 |
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