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Asymmetric hetero-Diels–Alder reaction catalyzed by dirhodium(II) carboxamidates
Chiral dirhodium(II) carboxamidates are highly efficient catalysts for reactions between a variety of aldehydes and activated dienes. Catalyst loadings as low at 0.01 mol % have been realized with enantioselectivities up to 97%. Kinetic investigations reveal a pronounced electronic influence on the...
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| Autores principales: | , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
National Academy of Sciences
2004
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC397391/ https://ncbi.nlm.nih.gov/pubmed/15060277 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0307025101 |
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