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Origins of Stereoselectivity in the trans-Diels-Alder Paradigm

The regioselectivity and stereoselectivity aspects of the Diels-Alder/radical hydrodenitration reaction sequence leading to trans-fused ring systems have been investigated with density functional calculations. A continuum of transition structures representing Diels-Alder and hetero-Diels-Alder cyclo...

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Détails bibliographiques
Auteurs principaux: Paton, Robert S., Mackey, Joel L., Kim, Woo Han, Lee, Jun Hee, Danishefsky, Samuel J., Houk, K. N.
Format: Artigo
Langue:Inglês
Publié: 2010
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2908589/
https://ncbi.nlm.nih.gov/pubmed/20557046
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1009162
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