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Improved Dienophilicity of Nitrocycloalkenes: Prospects for the Development of a trans-Diels-Alder Paradigm

The development of an efficient and stereoselective trans-Diels-Alder paradigm is described. A central element of this transformation is the introduction of a temporary dienophilic functionality (A), which serves both to activate the substrate for Diels-Alder cycloaddtion and, through its subsequent...

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Bibliografische gegevens
Hoofdauteurs: Kim, Woo Han, Lee, Jun Hee, Danishefsky, Samuel J.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2009
Onderwerpen:
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2746560/
https://ncbi.nlm.nih.gov/pubmed/19685875
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9058926
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