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Silyl‐Phosphino‐Carbene Complexes of Uranium(IV)
Unprecedented silyl‐phosphino‐carbene complexes of uranium(IV) are presented, where before all covalent actinide–carbon double bonds were stabilised by phosphorus(V) substituents or restricted to matrix isolation experiments. Conversion of [U(BIPM(TMS))(Cl)(μ‐Cl)(2)Li(THF)(2)] (1, BIPM(TMS)=C(PPh(2)...
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| Publicado en: | Angew Chem Int Ed Engl |
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| Autores principales: | , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
John Wiley and Sons Inc.
2018
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6001699/ https://ncbi.nlm.nih.gov/pubmed/29534326 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201802080 |
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