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Silyl‐Phosphino‐Carbene Complexes of Uranium(IV)
Unprecedented silyl‐phosphino‐carbene complexes of uranium(IV) are presented, where before all covalent actinide–carbon double bonds were stabilised by phosphorus(V) substituents or restricted to matrix isolation experiments. Conversion of [U(BIPM(TMS))(Cl)(μ‐Cl)(2)Li(THF)(2)] (1, BIPM(TMS)=C(PPh(2)...
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| Izdano u: | Angew Chem Int Ed Engl |
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| Glavni autori: | , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
John Wiley and Sons Inc.
2018
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6001699/ https://ncbi.nlm.nih.gov/pubmed/29534326 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201802080 |
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