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A Very Short Uranium(IV)–Rhodium(I) Bond with Net Double‐Dative Bonding Character

Reaction of [U{C(SiMe(3))(PPh(2))}(BIPM)(μ‐Cl)Li(TMEDA)(μ‐TMEDA)(0.5)](2) (BIPM=C(PPh(2)NSiMe(3))(2); TMEDA=Me(2)NCH(2)CH(2)NMe(2)) with [Rh(μ‐Cl)(COD)](2) (COD=cyclooctadiene) affords the heterotrimetallic U(IV)−Rh(I) (2) complex [U(Cl)(2){C(PPh(2)NSiMe(3))(PPh[C(6)H(4)]NSiMe(3))}{Rh(COD)}{Rh(CH(Si...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Angew Chem Int Ed Engl
Egile Nagusiak: Lu, Erli, Wooles, Ashley J., Gregson, Matthew, Cobb, Philip J., Liddle, Stephen T.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: John Wiley and Sons Inc. 2018
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC6055764/
https://ncbi.nlm.nih.gov/pubmed/29665209
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201803493
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