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A Very Short Uranium(IV)–Rhodium(I) Bond with Net Double‐Dative Bonding Character
Reaction of [U{C(SiMe(3))(PPh(2))}(BIPM)(μ‐Cl)Li(TMEDA)(μ‐TMEDA)(0.5)](2) (BIPM=C(PPh(2)NSiMe(3))(2); TMEDA=Me(2)NCH(2)CH(2)NMe(2)) with [Rh(μ‐Cl)(COD)](2) (COD=cyclooctadiene) affords the heterotrimetallic U(IV)−Rh(I) (2) complex [U(Cl)(2){C(PPh(2)NSiMe(3))(PPh[C(6)H(4)]NSiMe(3))}{Rh(COD)}{Rh(CH(Si...
Gorde:
| Argitaratua izan da: | Angew Chem Int Ed Engl |
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| Egile Nagusiak: | , , , , |
| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
John Wiley and Sons Inc.
2018
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6055764/ https://ncbi.nlm.nih.gov/pubmed/29665209 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201803493 |
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