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Double dative bond between divalent carbon(0) and uranium

Dative bonds between p- and d-block atoms are common but species containing a double dative bond, which donate two-electron pairs to the same acceptor, are far less common. The synthesis of complexes between UCl(4) and carbodiphosphoranes (CDP), which formally possess double dative bonds Cl(4)U⇇CDP,...

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Detalles Bibliográficos
Publicado en:Nat Commun
Main Authors: Su, Wei, Pan, Sudip, Sun, Xiong, Wang, Shuao, Zhao, Lili, Frenking, Gernot, Zhu, Congqing
Formato: Artigo
Idioma:Inglês
Publicado: Nature Publishing Group UK 2018
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6258733/
https://ncbi.nlm.nih.gov/pubmed/30479324
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-07377-6
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