d–d Dative Bonding Between Iron and the Alkaline‐Earth Metals Calcium, Strontium, and Barium

Double deprotonation of the diamine 1,1′‐(tBuCH(2)NH)‐ferrocene (1‐H(2)) by alkaline‐earth (Ae) or Eu(II) metal reagents gave the complexes 1‐Ae (Ae=Mg, Ca, Sr, Ba) and 1‐Eu. 1‐Mg crystallized as a monomer while the heavier complexes crystallized as dimers. The Fe⋅⋅⋅Mg distance in 1‐Mg is too long f...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Stegner, Philipp, Färber, Christian, Oetzel, Jan, Siemeling, Ulrich, Wiesinger, Michael, Langer, Jens, Pan, Sudip, Holzmann, Nicole, Frenking, Gernot, Albold, Uta, Sarkar, Biprajit, Harder, Sjoerd
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Research Articles
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496664/
https://ncbi.nlm.nih.gov/pubmed/32463527
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202005774
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