d–d Dative Bonding Between Iron and the Alkaline‐Earth Metals Calcium, Strontium, and Barium

Double deprotonation of the diamine 1,1′‐(tBuCH(2)NH)‐ferrocene (1‐H(2)) by alkaline‐earth (Ae) or Eu(II) metal reagents gave the complexes 1‐Ae (Ae=Mg, Ca, Sr, Ba) and 1‐Eu. 1‐Mg crystallized as a monomer while the heavier complexes crystallized as dimers. The Fe⋅⋅⋅Mg distance in 1‐Mg is too long f...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Stegner, Philipp, Färber, Christian, Oetzel, Jan, Siemeling, Ulrich, Wiesinger, Michael, Langer, Jens, Pan, Sudip, Holzmann, Nicole, Frenking, Gernot, Albold, Uta, Sarkar, Biprajit, Harder, Sjoerd
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2020
Fag:
Research Articles
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496664/
https://ncbi.nlm.nih.gov/pubmed/32463527
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202005774
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