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Heteroleptic actinocenes: a thorium(iv)–cyclobutadienyl–cyclooctatetraenyl–di-potassium-cyclooctatetraenyl complex
Despite the vast array of η(n)-carbocyclic C(5–8) complexes reported for actinides, cyclobutadienyl (C(4)) remain exceedingly rare, being restricted to six uranium examples. Here, overcoming the inherent challenges of installing highly reducing C(4)-ligands onto actinides when using polar starting m...
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| Publié dans: | Chem Sci |
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| Auteurs principaux: | , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
The Royal Society of Chemistry
2020
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8159314/ https://ncbi.nlm.nih.gov/pubmed/34094128 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02479a |
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