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Assessing crystal field and magnetic interactions in diuranium-μ-chalcogenide triamidoamine complexes with U(IV)–E–U(IV) cores (E = S, Se, Te): implications for determining the presence or absence of actinide–actinide magnetic exchange

We report the synthesis and characterisation of a family of diuranium(iv)-μ-chalcogenide complexes including a detailed examination of their electronic structures and magnetic behaviours. Treatment of [U(Tren(TIPS))] [1, Tren(TIPS) = N(CH(2)CH(2)NSiPr(i) (3))(3)] with Ph(3)PS, selenium or tellurium...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Chem Sci
Prif Awduron: Gardner, Benedict M., King, David M., Tuna, Floriana, Wooles, Ashley J., Chilton, Nicholas F., Liddle, Stephen T.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: Royal Society of Chemistry 2017
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC5628351/
https://ncbi.nlm.nih.gov/pubmed/28989654
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc01998j
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