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Terminal Parent Phosphanide and Phosphinidene Complexes of Zirconium(IV)
The reaction of [Zr(Tren(DMBS))(Cl)] [Zr1; Tren(DMBS)=N(CH(2)CH(2)NSiMe(2)Bu(t))(3)] with NaPH(2) gave the terminal parent phosphanide complex [Zr(Tren(DMBS))(PH(2))] [Zr2; Zr−P=2.690(2) Å]. Treatment of Zr2 with one equivalent of KCH(2)C(6)H(5) and two equivalents of benzo‐15‐crown‐5 ether (B15C5)...
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| 出版年: | Angew Chem Int Ed Engl |
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| 主要な著者: | , , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
John Wiley and Sons Inc.
2017
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5575506/ https://ncbi.nlm.nih.gov/pubmed/28489308 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201703870 |
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