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Coupling of sterically demanding peptides by β-thiolactone-mediated native chemical ligation

The ligation of sterically demanding peptidyl sites such as those involving Val–Val and Val–Pro linkages has proven to be extremely challenging with conventional NCL methods that rely on exogenous thiol additives. Herein, we report an efficient β-thiolactone-mediated additive-free NCL protocol that...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Chen, Huan, Xiao, Yunxian, Yuan, Ning, Weng, Jiaping, Gao, Pengcheng, Breindel, Leonard, Shekhtman, Alexander, Zhang, Qiang
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5892351/
https://ncbi.nlm.nih.gov/pubmed/29675245
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04744d
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