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Enantioselective Intermolecular [2+2] Photocycloaddition Reaction of Cyclic Enones and Its Application in a Synthesis of (−)-Grandisol
[Image: see text] The intermolecular [2+2] photocycloaddition of typical cyclic α,β-unsaturated enones, such as 2-cyclohexenone, with olefins was performed in moderate to good yields (42–82%) and with high enantioselectivity (82%–96% ee). An unusual substitution pattern at the chiral oxazaborolidine...
Gardado en:
| Publicado en: | J Am Chem Soc |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
American Chemical
Society
2018
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| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5849358/ https://ncbi.nlm.nih.gov/pubmed/29458250 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b01011 |
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