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Brønsted Acid Catalysis in Visible‐Light‐Induced [2+2] Photocycloaddition Reactions of Enone Dithianes

1,3‐Dithiane‐protected enones (enone dithianes) were found to undergo an intramolecular [2+2] photocycloaddition under visible‐light irradiation (λ=405 nm) in the presence of a Brønsted acid (7.5–10 mol %). Key to the success of the reaction is presumably the formation of colored thionium ions, whic...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Brenninger, Christoph, Pöthig, Alexander, Bach, Thorsten
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5396283/
https://ncbi.nlm.nih.gov/pubmed/28319302
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201700837
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