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Evidence for Triplet Sensitization in the Visible‐Light‐Induced [2+2] Photocycloaddition of Eniminium Ions

Εniminium ions were prepared from the corresponding α,β‐unsaturated carbonyl compounds (enones and enals), and were found to be promoted to their respective triplet states by energy transfer. The photoexcited intermediates underwent intra‐ or intermolecular [2+2] photocycloaddition in good yields (5...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Hörmann, Fabian M., Chung, Tim S., Rodriguez, Elsa, Jakob, Matthias, Bach, Thorsten
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5768022/
https://ncbi.nlm.nih.gov/pubmed/29178574
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201710441
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