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Enantioselective Intermolecular [2 + 2] Photocycloaddition Reactions of 2(1H)-Quinolones Induced by Visible Light Irradiation

[Image: see text] In the presence of a chiral thioxanthone catalyst (10 mol %) the title compounds underwent a clean intermolecular [2 + 2] photocycloaddition with electron-deficient olefins at λ = 419 nm. The reactions not only proceeded with excellent regio- and diastereoselectivity but also deliv...

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Publicat a:J Am Chem Soc
Autors principals: Tröster, Andreas, Alonso, Rafael, Bauer, Andreas, Bach, Thorsten
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2016
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4929526/
https://ncbi.nlm.nih.gov/pubmed/27268908
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b03221
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