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A Chiral Thiourea as a Template for Enantioselective Intramolecular [2 + 2] Photocycloaddition Reactions

[Image: see text] A chiral (1R,2R)-diaminocyclohexane-derived bisthiourea was found to exhibit a significant asymmetric induction in the intramolecular [2 + 2] photocycloaddition of 2,3-dihydropyridone-5-carboxylates. Under optimized conditions, the reaction was performed with visible light employin...

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Detalhes bibliográficos
Publicado no:J Org Chem
Main Authors: Mayr, Florian, Brimioulle, Richard, Bach, Thorsten
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2016
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4994062/
https://ncbi.nlm.nih.gov/pubmed/27258626
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.6b01039
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