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Intramolecular [2+2] Photocycloaddition of Cyclic Enones: Selectivity Control by Lewis Acids and Mechanistic Implications

The intramolecular [2+2] photocycloaddition of 3‐alkenyl‐2‐cycloalkenones was performed in an enantioselective fashion (nine representative examples, 54–86 % yield, 76–96 % ee) upon irradiation at λ=366 nm in the presence of an AlBr(3)‐activated oxazaborolidine as the Lewis acid. An extensive screen...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Veröffentlicht in:Chemistry
Hauptverfasser: Poplata, Saner, Bauer, Andreas, Storch, Golo, Bach, Thorsten
Format: Artigo
Sprache:Inglês
Veröffentlicht: John Wiley and Sons Inc. 2019
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6618137/
https://ncbi.nlm.nih.gov/pubmed/30983074
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201901304
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