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A Stereoselective [3+1] Ring Expansion for the Synthesis of Highly-Substituted Methylene Azetidines
The reaction of rhodium-bound carbenes with strained bicyclic methylene aziridines results in a formal [3+1] ring expansion to yield highly-substituted methylene azetidines with excellent regio-and stereoselectivity. The reaction appears to proceed through an ylide-type mechanism, where the unique s...
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| Publicado en: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2017
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5693379/ https://ncbi.nlm.nih.gov/pubmed/28834110 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201705202 |
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