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Ring Expansion of Bicyclic Methyleneaziridines via Concerted, Near-Barrierless [2,3]-Stevens Rearrangements of Aziridinium Ylides

The synthesis of densely functionalized azetidinesin a highly stereocontrolled manner is challenging, but interest in the bioactivities of these small heterocycles has stimulated methods for their preparation. We recently reported a one-carbon ring expansion of bicyclic methylene aziridines under di...

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Detalhes bibliográficos
Publicado no:ACS Catal
Main Authors: Schmid, Steven C., Guzei, Ilia A., Fernández, Israel, Schomaker, Jennifer M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6173328/
https://ncbi.nlm.nih.gov/pubmed/30294503
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b02206
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