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Oxidative Allene Amination for the Synthesis of Azetidin-3-ones
Regioselectivity in the aziridination of silyl-substituted homoallenic sulfamates is readily diverted to the distal double bond of the allene to yield endocyclic bicyclic methyleneaziridines with excellent stereocontrol. Subsequent reaction with electrophilic oxygen sources initiates facile rearrang...
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| Pubblicato in: | Angew Chem Int Ed Engl |
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| Autori principali: | , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2015
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4701577/ https://ncbi.nlm.nih.gov/pubmed/26387687 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201504723 |
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