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Enantioselective Formation of CF(3)-Bearing All-Carbon Quaternary Stereocenters via C-H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation
Using an iridium catalyst modified by PhanePhos, CF(3)-allenes react with methanol to form branched products of hydrohydroxymethylation as single regioisomers with excellent levels of enantiomeric enrichment. This hydrogen auto-transfer process enables catalytic enantioselective formation of acyclic...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2017
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5651675/ https://ncbi.nlm.nih.gov/pubmed/28603973 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b04374 |
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