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Ruthenium Catalyzed Reductive Coupling of Paraformaldehyde to Trifluoromethyl Allenes: CF(3)-Bearing All-Carbon Quaternary Centers
[Image: see text] Trifluoromethyl substituted allenes engage in ruthenium catalyzed reductive couplings with paraformaldehyde to form products of hydrohydroxymethylation as single regioisomers. This method enables generation of CF(3)-bearing all-carbon quaternary stereocenters.
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3779475/ https://ncbi.nlm.nih.gov/pubmed/23841678 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol401771a |
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