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Direct Ruthenium Catalyzed C-C Coupling of Ethanol: Diene Hydro-Hydroxyethylation to Form All Carbon Quaternary Centers
[Image: see text] Under ruthenium catalyzed transfer hydrogenation conditions, direct C-C coupling of ethanol and 2-substituted dienes occurs to furnish products of hydro-hydroxyethylation: anti-configured neopentyl homoallylic alcohols. Identical adducts are generated from acetaldehyde under relate...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2884076/ https://ncbi.nlm.nih.gov/pubmed/20491487 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol101077v |
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