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All Carbon Quaternary Centers via Ruthenium-Catalyzed Hydroxymethylation of 2-Substituted Butadienes Mediated by Formaldehyde: Beyond Hydroformylation
[Image: see text] Ruthenium catalyzed transfer hydrogenation of 2-substituted dienes 1a-1i in the presence of paraformaldehyde results in reductive coupling at the 2-position to furnish products of hydroxymethylation 3a-3i, which embody all carbon quaternary centers. Reductive coupling of diene 1g t...
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| Asıl Yazarlar: | , , , |
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| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
2009
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2737081/ https://ncbi.nlm.nih.gov/pubmed/19594163 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja904124b |
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