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Ruthenium Catalyzed C-C Bond Formation via Transfer Hydrogenation: Branch-Selective Reductive Coupling of Allenes to Paraformaldehyde and Higher Aldehydes
[Image: see text] Upon exposure to the conditions of ruthenium catalyzed transfer hydrogenation employing isopropanol as the terminal reductant, 1,1-disubstituted allenes 1a-1h engage in reductive coupling to paraformaldehyde to furnish homoallylic alcohols 2a-2h. Under identical transfer hydrogenat...
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| Autors principals: | , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2008
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2845390/ https://ncbi.nlm.nih.gov/pubmed/18533665 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol800836v |
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