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Ruthenium Catalyzed C-C Bond Formation via Transfer Hydrogenation: Branch-Selective Reductive Coupling of Allenes to Paraformaldehyde and Higher Aldehydes

[Image: see text] Upon exposure to the conditions of ruthenium catalyzed transfer hydrogenation employing isopropanol as the terminal reductant, 1,1-disubstituted allenes 1a-1h engage in reductive coupling to paraformaldehyde to furnish homoallylic alcohols 2a-2h. Under identical transfer hydrogenat...

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Bibliographic Details
Main Authors: Ngai, Ming-Yu, Skucas, Eduardas, Krische, Michael J.
Format: Artigo
Language:Inglês
Published: 2008
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2845390/
https://ncbi.nlm.nih.gov/pubmed/18533665
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol800836v
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