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Formation of C-C Bonds via Ruthenium Catalyzed Transfer Hydrogenation: Carbonyl Addition from the Alcohol or Aldehyde Oxidation Level

Under the conditions of ruthenium catalyzed transfer hydrogenation employing isopropanol as terminal reductant, π-unsaturated compounds (1,3-dienes, allenes, 1,3-enynes and alkynes) reductively couple to aldehydes to furnish products of carbonyl addition. In the absence of isopropanol, π-unsaturated...

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Bibliographic Details
Main Authors: Shibahara, Fumitoshi, Krische, Michael J.
Format: Artigo
Language:Inglês
Published: 2008
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3172969/
https://ncbi.nlm.nih.gov/pubmed/21927534
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1246/cl.2008.1102
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