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anti-Aminoallylation of Aldehydes via Ruthenium Catalyzed Transfer Hydrogenative Coupling of Sulfonamido-Allenes: 1,2-Aminoalcohols

[Image: see text] Ruthenium catalyzed transfer hydrogenation of N-sulfonamido allene 1e in the presence of aromatic aldehydes 2a-2f, α,β-unsaturated aldehydes 2g-2i and aliphatic aldehydes 2j-2l results in reductive coupling to furnish anti-aminoallylation products 3a-3l. Reductive coupling of allen...

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Sonraí Bibleagrafaíochta
Main Authors: Skucas, Eduardas, Zbieg, Jason R., Krische, Michael J.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2009
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2676672/
https://ncbi.nlm.nih.gov/pubmed/19317402
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja900827p
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