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Allenamide Hydro-Hydroxyalkylation: 1,2-Aminoalcohols via Ruthenium Catalyzed Carbonyl anti-Aminoallylation
[Image: see text] Exposure of alcohols to allenamides in the presence of RuHCl(CO)(PPh(3))(3) and dippf [dippf = bis(diisopropylphosphino)ferrocene] results in hydrogen transfer to generate aldehyde-allylruthenium pairs, which engage in C-C coupling to form products of carbonyl aminoallylation as si...
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| Glavni autori: | , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2010
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2881554/ https://ncbi.nlm.nih.gov/pubmed/20459077 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol1007235 |
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