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Iridium Catalyzed Hydro-hydroxyalkylation of Butadiene: Carbonyl Crotylation
Exposure of alcohols 1a-1i to butadiene in the presence of a cyclometallated iridium catalyzed derived from allyl acetate, 4-methoxy-3-nitrobenzoic acid and BIPHEP (2,2′-bis(diphenylphosphino)biphenyl) results in hydrogen transfer to generate aldehyde-allyliridium pairs, which engage in C-C coupling...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2010
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3001632/ https://ncbi.nlm.nih.gov/pubmed/21165157 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201000599 |
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