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Iridium Catalyzed Hydro-hydroxyalkylation of Butadiene: Carbonyl Crotylation

Exposure of alcohols 1a-1i to butadiene in the presence of a cyclometallated iridium catalyzed derived from allyl acetate, 4-methoxy-3-nitrobenzoic acid and BIPHEP (2,2′-bis(diphenylphosphino)biphenyl) results in hydrogen transfer to generate aldehyde-allyliridium pairs, which engage in C-C coupling...

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Detalhes bibliográficos
Main Authors: Zbieg, Jason R., Fukuzumi, Takeo, Krische, Michael J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3001632/
https://ncbi.nlm.nih.gov/pubmed/21165157
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201000599
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